Literature DB >> 15306917

Platinum catalysed 3,4- and 1,4-diboration of alpha,beta-unsaturated carbonyl compounds using bis-pinacolatodiboron.

Nathan J Bell1, Andrew J Cox, Neil R Cameron, John S O Evans, Todd B Marder, Marcel A Duin, Cornelis J Elsevier, Xavier Baucherel, Arran A D Tulloch, Robert P Tooze.   

Abstract

Bis-pinacolatodiboron reacts with [small alpha],[small beta]-unsaturated carbonyl compounds to give 1,4- and unprecedented 3,4-additions in the presence of a second generation Pt(0) catalyst at ambient temperature.

Entities:  

Year:  2004        PMID： 15306917     DOI： 10.1039/b406052k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  12 in total

1.  Copper-catalyzed β-boration of α,β-unsaturated carbonyl compounds with tetrahydroxydiborane.

Authors:  Gary A Molander; Silas A McKee
Journal:  Org Lett       Date:  2011-08-05       Impact factor: 6.005

2.  Diastereoselective construction of functionalized homoallylic alcohols by Ni-catalyzed diboron-promoted coupling of dienes and aldehydes.

Authors:  Hee Yeon Cho; James P Morken
Journal:  J Am Chem Soc       Date:  2008-12-03       Impact factor: 15.419

3.  Use of potassium beta-trifluoroborato amides in Suzuki-Miyaura cross-coupling reactions.

Authors:  Gary A Molander; Ludivine Jean-Gérard
Journal:  J Org Chem       Date:  2009-08-07       Impact factor: 4.354

4.  Scope and mechanism of the Pt-catalyzed enantioselective diboration of monosubstituted alkenes.

Authors:  John R Coombs; Fredrik Haeffner; Laura T Kliman; James P Morken
Journal:  J Am Chem Soc       Date:  2013-07-18       Impact factor: 15.419

5.  Synthesis and Suzuki-Miyaura Cross-Coupling of Enantioenriched Secondary Potassium β-Trifluoroboratoamides: Catalytic, Asymmetric Conjugate Addition of Bisboronic Acid and Tetrakis(dimethylamino)diboron to α,β-Unsaturated Carbonyl Compounds.

Authors:  Gary A Molander; Steven R Wisniewski; Mona Hosseini-Sarvari
Journal:  Adv Synth Catal       Date:  2013-10-11       Impact factor: 5.837

6.  Efficient C-B bond formation promoted by N-heterocyclic carbenes: synthesis of tertiary and quaternary B-substituted carbons through metal-free catalytic boron conjugate additions to cyclic and acyclic alpha,beta-unsaturated carbonyls.

Authors:  Kang-sang Lee; Adil R Zhugralin; Amir H Hoveyda
Journal:  J Am Chem Soc       Date:  2009-06-03       Impact factor: 15.419

Review 7.  Diastereoselective and enantioselective conjugate addition reactions utilizing α,β-unsaturated amides and lactams.

Authors:  Katherine M Byrd
Journal:  Beilstein J Org Chem       Date:  2015-04-23       Impact factor: 2.883

8.  α,β-Enone Borylation by Bis(Pinacolato)Diboron Catalyzed by Cu3(BTC)2 Using Cesium Carbonate as a Base.

Authors:  Amarajothi Dhakshinamoorthy; Mercedes Alvaro; Abdullah M Asiri; Hermenegildo Garcia
Journal:  Nanomaterials (Basel)       Date:  2021-05-25       Impact factor: 5.076

9.  C-Boron Enolates Enable Palladium Catalyzed Carboboration of Internal 1,3-Enynes.

Authors:  Ziyong Wang; Jason Wu; Walid Lamine; Bo Li; Jean-Marc Sotiropoulos; Anna Chrostowska; Karinne Miqueu; Shih-Yuan Liu
Journal:  Angew Chem Int Ed Engl       Date:  2021-08-31       Impact factor: 16.823

10.  Borylation of α,β-Unsaturated Acceptors by Chitosan Composite Film Supported Copper Nanoparticles.

Authors:  Wu Wen; Biao Han; Feng Yan; Liang Ding; Bojie Li; Liansheng Wang; Lei Zhu
Journal:  Nanomaterials (Basel)       Date:  2018-05-14       Impact factor: 5.076
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