Literature DB >> 15306903

New perspectives in hydroformylation: a para-hydrogen study.

Cyril Godard1, Simon B Duckett, Celine Henry, Stacey Polas, Robert Toose, Adrian C Whitwood.   

Abstract

NMR studies on the reaction of Ir(CO)(PPh(3))(2)(eta(3)-C(3)H(5)) with para-H(2) and CO enable the complete mapping of the hydroformylation mechanism for an iridium monohydride catalyst via the detection of species which include iridium acyl and alkyl dihydride intermediates.

Entities:  

Year:  2004        PMID： 15306903     DOI： 10.1039/b404547e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

Review 1.  Advancing homogeneous catalysis for parahydrogen-derived hyperpolarisation and its NMR applications.

Authors:  Ben J Tickner; Vladimir V Zhivonitko
Journal:  Chem Sci       Date:  2022-03-22       Impact factor: 9.969

2.  Using hyperpolarised NMR and DFT to rationalise the unexpected hydrogenation of quinazoline to 3,4-dihydroquinazoline.

Authors:  Josh E Richards; Alexander J J Hooper; Oliver W Bayfield; Martin C R Cockett; Gordon J Dear; A Jonathon Holmes; Richard O John; Ryan E Mewis; Natalie Pridmore; Andy D Roberts; Adrian C Whitwood; Simon B Duckett
Journal:  Chem Commun (Camb)       Date:  2018-09-11       Impact factor: 6.222
  2 in total

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