| Literature DB >> 15281751 |
Jackline E Dalgard1, Scott D Rychnovsky.
Abstract
The transannular cyclization of an enantioenriched cyclodecenyl radical proceeds in a 5-exo fashion to produce scalemic bicyclo[5.3.0]decanes. This cyclization is notable because it demonstrates chirality transfer through conformational memory of an unstabilized secondary radical. [reaction: see text]Entities:
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Year: 2004 PMID： 15281751 DOI： 10.1021/ol049038x
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005