Literature DB >> 15278175

Preparation and structural characterisation of methoxybis(trimethylsilyl)silyl potassium and its condensation product.

Pravin R Likhar1, Michaela Zirngast, Judith Baumgartner, Christoph Marschner.   

Abstract

Depending on the conditions the reaction of tris(trimethylsilyl)methoxysilane (1) with potassium tert-butoxide either in benzene and in the presence of 18-crown-6 or in THF gives either the crown ether adduct of potassium-methoxybis(trimethylsilyl)silane (2), or 2-methoxytetrakis(trimethylsilyl)disilanyl potassium (3).

Entities:  

Year:  2004        PMID： 15278175     DOI： 10.1039/b406074a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  A new exploration of the addition reaction of the silylenoid H2SiLiF with ethylene.

Authors:  Mingxia Zhang; Wenzuo Li; Qingzhong Li; Jianbo Cheng
Journal:  J Mol Model       Date:  2015-07-21       Impact factor: 1.810

2.  Oligosilanylsilatranes.

Authors:  Mohammad Aghazadeh Meshgi; Judith Baumgartner; Christoph Marschner
Journal:  Organometallics       Date:  2015-07-28       Impact factor: 3.876

3.  Using Functionalized Silyl Ligands To Suppress Solvent Coordination to Silyl Lanthanide(II) Complexes.

Authors:  Rainer Zitz; Johann Hlina; Mohammad Aghazadeh Meshgi; Heinz Krenn; Christoph Marschner; Tibor Szilvási; Judith Baumgartner
Journal:  Inorg Chem       Date:  2017-04-11       Impact factor: 5.165

4.  Group 4 Metal and Lanthanide Complexes in the Oxidation State +3 with Tris(trimethylsilyl)silyl Ligands.

Authors:  Rainer Zitz; Johann Hlina; Henning Arp; Dominik Kinschel; Christoph Marschner; Judith Baumgartner
Journal:  Inorg Chem       Date:  2019-05-08       Impact factor: 5.165

5.  An Anionic Amido-Substituted Seven-Vertex Siliconoid Cluster.

Authors:  Jan Keuter; Maria Dimitrova; Oliver Janka; Alexander Hepp; Raphael J F Berger; Felicitas Lips
Journal:  Chemistry       Date:  2022-06-30       Impact factor: 5.020

6.  β-Amino- and Alkoxy-Substituted Disilanides.

Authors:  Istvan Balatoni; Johann Hlina; Rainer Zitz; Alexander Pöcheim; Judith Baumgartner; Christoph Marschner
Journal:  Molecules       Date:  2019-10-23       Impact factor: 4.411
  6 in total

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