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Literature DB >> 15278167

Protonation of a lanthanum phosphide-alkyl occurs at the P-La not the C-La bond: isolation of a cationic lanthanum alkyl complex.

Keith Izod¹, Stephen T Liddle, William Clegg.

Abstract

Protonation of the heteroleptic, cyclometalated lanthanum phosphide complex [((Me3Si)2CH)(C6H4-2-CH2NMe2)P]La(THF)[P(C6H4-2-CH2NMe2)(CH(SiMe3)(SiMe2CH2))] with [Et3NH][BPh4] yields the cationic alkyllanthanum complex [(THF)4La[P(C6H4-2-CH2NMe2)(CH(SiMe3)(SiMe2CH2))]][BPh4].

Entities: Chemical

Year: 2004 PMID： 15278167 DOI： 10.1039/b404188g

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

2 in total

1. Novel polymerization catalysts and hydride clusters from rare-earth metal dialkyls.

Authors: Masayoshi Nishiura; Zhaomin Hou
Journal: Nat Chem Date: 2010-03-24 Impact factor: 24.427

2. An actinide Zintl cluster: a tris(triamidouranium)μ3-η2:η2:η2-heptaphosphanortricyclane and its diverse synthetic utility.

Authors: Dipti Patel; Floriana Tuna; Eric J L McInnes; William Lewis; Alexander J Blake; Stephen T Liddle
Journal: Angew Chem Int Ed Engl Date: 2013-10-14 Impact factor: 15.336

2 in total