Literature DB >> 15278154

Highly selective formation of linear esters from terminal and internal alkenes catalysed by palladium complexes of bis-(di-tert-butylphosphinomethyl)benzene.

Cristina Jimenez Rodriguez1, Douglas F Foster, Graham R Eastham, David J Cole-Hamilton.   

Abstract

The methoxycarbonylation of terminal or internal alkenes catalysed by palladium complexes of bis-(di-tert-butylphosphinomethyl)benzene under mild conditions leads to linear esters in 99% selectivity via a hydride mechanism.

Entities:  

Year:  2004        PMID: 15278154     DOI: 10.1039/b404783d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  8 in total

1.  The scope and mechanism of palladium-catalysed Markovnikov alkoxycarbonylation of alkenes.

Authors:  Haoquan Li; Kaiwu Dong; Haijun Jiao; Helfried Neumann; Ralf Jackstell; Matthias Beller
Journal:  Nat Chem       Date:  2016-09-05       Impact factor: 24.427

Review 2.  Remote functionalization through alkene isomerization.

Authors:  Alexandre Vasseur; Jeffrey Bruffaerts; Ilan Marek
Journal:  Nat Chem       Date:  2016-03       Impact factor: 24.427

3.  Highly active and efficient catalysts for alkoxycarbonylation of alkenes.

Authors:  Kaiwu Dong; Xianjie Fang; Samet Gülak; Robert Franke; Anke Spannenberg; Helfried Neumann; Ralf Jackstell; Matthias Beller
Journal:  Nat Commun       Date:  2017-01-25       Impact factor: 14.919

4.  Biofuel by isomerizing metathesis of rapeseed oil esters with (bio)ethylene for use in contemporary diesel engines.

Authors:  Kai F Pfister; Sabrina Baader; Mathias Baader; Silvia Berndt; Lukas J Goossen
Journal:  Sci Adv       Date:  2017-06-16       Impact factor: 14.136

5.  Cooperative catalytic methoxycarbonylation of alkenes: uncovering the role of palladium complexes with hemilabile ligands.

Authors:  Kaiwu Dong; Rui Sang; Zhihong Wei; Jie Liu; Ricarda Dühren; Anke Spannenberg; Haijun Jiao; Helfried Neumann; Ralf Jackstell; Robert Franke; Matthias Beller
Journal:  Chem Sci       Date:  2018-02-07       Impact factor: 9.825

Review 6.  Carbonylation of ethene catalysed by Pd(II)-phosphine complexes.

Authors:  Gianni Cavinato; Luigi Toniolo
Journal:  Molecules       Date:  2014-09-22       Impact factor: 4.411

7.  Toward Green Acylation of (Hetero)arenes: Palladium-Catalyzed Carbonylation of Olefins to Ketones.

Authors:  Jie Liu; Zhihong Wei; Haijun Jiao; Ralf Jackstell; Matthias Beller
Journal:  ACS Cent Sci       Date:  2017-11-16       Impact factor: 14.553

8.  A General and Highly Selective Palladium-Catalyzed Hydroamidation of 1,3-Diynes.

Authors:  Jiawang Liu; Carolin Schneider; Ji Yang; Zhihong Wei; Haijun Jiao; Robert Franke; Ralf Jackstell; Matthias Beller
Journal:  Angew Chem Int Ed Engl       Date:  2020-10-27       Impact factor: 15.336

  8 in total

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