Literature DB >> 15268433

The Enskog-type theory of the velocity autocorrelations in the two-dimensional nematic of hard needles.

Agnieszka Chrzanowska1.   

Abstract

As it was shown from molecular dynamics of two-dimensional hard needles, the uniaxial velocity autocorrelation function (VACF) of this system exhibits a two time scale character. This corresponds to the symmetry of the particles. In this paper we provide a theory of the Enskog type that corroborates the idea that the VACF can be successfully described as a sum of two single decays. From the comparison between molecular dynamics and theoretical results, we show that the Enskog approach is a satisfactory kinetic theory, which functions as well in the nematic as in the isotropic phase. Different properties of VACFs have been investigated, in particular, the dependence on the orientational order, temperature, and particles' inertness.

Year:  2004        PMID: 15268433     DOI: 10.1063/1.1640350

Source DB:  PubMed          Journal:  J Chem Phys        ISSN: 0021-9606            Impact factor:   3.488


  2 in total

1.  Temporal and structural characteristics of a two-dimensional gas of hard needles.

Authors:  M E Foulaadvand; M Yarifard
Journal:  Eur Phys J E Soft Matter       Date:  2011-04-21       Impact factor: 1.890

2.  Comment on the diffusion properties presented in "Temporal and structural characteristics of a two-dimensional gas of hard needles".

Authors:  Agnieszka Chrzanowska
Journal:  Eur Phys J E Soft Matter       Date:  2012-12-21       Impact factor: 1.890

  2 in total

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