| Literature DB >> 15264800 |
Yasujiro Murata1, Fuyong Cheng, Toshikazu Kitagawa, Koichi Komatsu.
Abstract
A novel fullerenyl cation (EtO)2P+(OH)CH2-C60+ was generated by simply dissolving the monofunctionalized hydrofullerene RC60-H or singly bonded dimer RC60-C60R (R = CH2P(O)(OEt)2) in oxidizing acids such as H2SO4 and FSO3H. The cation was also formed in CH2Cl2 by one-electron oxidation with aminium radical cation and was used for further functionalization of C60.Entities:
Year: 2004 PMID： 15264800 DOI： 10.1021/ja047483h
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419