Caulerpin.

The crystal structure of caulerpin (dimethyl 6,13-dihydrodibenzo[b,i]phenazine-5,12-dicarboxylate, C(24)H(18)N(2)O(4)), an indole alkaloid, reported in space group Cc with an acute beta angle, has been redetermined in the correct space group, C2/c. The molecule has twofold crystallographic symmetry and is composed of two essentially planar indole groups fused to an eight-membered cyclooctatetraene ring which adopts a boat conformation. The molecular dimensions are normal. The structure is stabilized by intermolecular and intramolecular interactions involving the indole N-H atom and carbonyl O atom [N.O 3.211 (4) and 2.836 (4) A].