Literature DB >> 15263109

micro-Terephthalato-bis[bis(1,10-phenanthroline)copper(I)] diperchlorate.

D Sun1, R Cao, Y Liang, M Hong, W Su, J Weng.   

Abstract

The title compound, [Cu(2)(C(8)H(4)O(4))(C(12)H(8)N(2))(4)](ClO(4))(2), was prepared from the hydrothermal reaction of CuCl(2), 1,4-dicyanobenzene, 1,10-phenanthroline and water at 443 K. The compound is a dimer in which the cation lies about an inversion center. The terephthalate moiety acts as a bridging ligand and the phenanthrolines as terminal ligands. The unique Cu atom is coordinated by two O and four N atoms in a distorted octahedral geometry, with Cu-O distances of 1.955 (2) and 2.815 (2) A, and Cu-N distances of 2.008 (2) to 2.216 (2) A.

Entities:  

Year:  2000        PMID: 15263109     DOI: 10.1107/S0108270100006119

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  Bis(2-amino-4-methyl-pyridinium) terephthalate tetra-hydrate.

Authors:  Madhukar Hemamalini; Hoong-Kun Fun
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-07-07
  1 in total

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