Literature DB >> 15257580

Dicopper-dioxygen complex supported by asymmetric pentapyridine dinucleating ligand.

Yoshimitsu Tachi1, Kazuki Aita, Shinichi Teramae, Fumito Tani, Yoshinori Naruta, Shunichi Fukuzumi, Shinobu Itoh.   

Abstract

A dicopper(I) complex supported by a novel asymmetric pentapyridine dinucleating ligand, consisting of tetradentate and tridentate metal-binding sites, has been synthesized and characterized. The dicopper(I) complex reacted with molecular oxygen at a low temperature to give an unprecedented mu-peroxo dicopper(II) complex presumably having a mu-eta1:eta2 binding mode, the spectroscopic features and the reactivity of which have been explored in detail. Copyright 2004 American Chemical Society

Entities:  

Year:  2004        PMID： 15257580     DOI： 10.1021/ic049524g

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  5 in total

1.  O2 chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O2 binding.

Authors:  Anna Company; Diana Lamata; Albert Poater; Miquel Solà; Elena V Rybak-Akimova; Lawrence Que; Xavier Fontrodona; Teodor Parella; Antoni Llobet; Miquel Costas
Journal:  Inorg Chem       Date:  2006-07-10       Impact factor: 5.165

Review 2.  Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O2 Model Systems to Organometallic Transformations.

Authors:  Rachel Trammell; Khashayar Rajabimoghadam; Isaac Garcia-Bosch
Journal:  Chem Rev       Date:  2019-01-30       Impact factor: 60.622

3.  Metal-dioxygen and metal-dinitrogen complexes: where are the electrons?

Authors:  Patrick L Holland
Journal:  Dalton Trans       Date:  2010-04-01       Impact factor: 4.390

Review 4.  Copper-Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity.

Authors:  Courtney E Elwell; Nicole L Gagnon; Benjamin D Neisen; Debanjan Dhar; Andrew D Spaeth; Gereon M Yee; William B Tolman
Journal:  Chem Rev       Date:  2017-01-19       Impact factor: 60.622

5.  O2 activation and selective phenolate ortho hydroxylation by an unsymmetric dicopper mu-eta1:eta1-peroxido complex.

Authors:  Isaac Garcia-Bosch; Anna Company; Jonathan R Frisch; Miquel Torrent-Sucarrat; Mar Cardellach; Ilaria Gamba; Mireia Güell; Luigi Casella; Lawrence Que; Xavi Ribas; Josep M Luis; Miquel Costas
Journal:  Angew Chem Int Ed Engl       Date:  2010-03-22       Impact factor: 15.336
  5 in total

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