| Literature DB >> 15255703 |
Joanne E Harvey1, Steven A Raw, Richard J K Taylor.
Abstract
[reaction: see text] The alpha,beta-unsaturated-gamma,delta-epoxyester 1 is a novel and versatile precursor to a wide variety of C-glycosides. For instance, treatment of Z-1 or E-1 with palladium(0) affords, stereospecifically, beta- or alpha-C-furanosides, respectively. In contrast, reaction of Z-1 or E-1 with base gives, stereoselectively, the beta- or alpha-C-pyranosides, respectively.Entities:
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Year: 2004 PMID： 15255703 DOI： 10.1021/ol0490678
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005