Literature DB >> 15255696

Efficient acyclic stereocontrol using the tethered aminohydroxylation reaction.

Timothy J Donohoe1, Peter D Johnson, Richard J Pye, Martine Keenan.   

Abstract

[reaction: see text] The tethered aminohydroxylation (TA) of acyclic allylic carbamates has been achieved in a stereospecific and stereoselective manner. Unusually high levels of stereocontrol were observed in the oxidation of 1,1-disubstituted substrates.

Entities:  

Year:  2004        PMID: 15255696     DOI: 10.1021/ol049136i

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  4 in total

1.  Synthesis of the dysiherbaine tetrahydropyran core utilizing improved tethered aminohydroxylation conditions.

Authors:  Christopher L Carroll; A Richard Chamberlin
Journal:  Tetrahedron Lett       Date:  2011-08-03       Impact factor: 2.415

2.  Synthesis of the dysiherbaine tetrahydropyran core employing a tethered aminohydroxylation reaction.

Authors:  Jamie L Cohen; A Richard Chamberlin
Journal:  Tetrahedron Lett       Date:  2007-04-02       Impact factor: 2.415

3.  Mechanistic analysis and optimization of the copper-catalyzed enantioselective intramolecular alkene aminooxygenation.

Authors:  Monissa C Paderes; Jerome B Keister; Sherry R Chemler
Journal:  J Org Chem       Date:  2012-12-28       Impact factor: 4.354

4.  Pyrrolidine and piperidine formation via copper(II) carboxylate-promoted intramolecular carboamination of unactivated olefins: diastereoselectivity and mechanism.

Authors:  Eric S Sherman; Peter H Fuller; Dhanalakshmi Kasi; Sherry R Chemler
Journal:  J Org Chem       Date:  2007-04-12       Impact factor: 4.354

  4 in total

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