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Literature DB >> 15252675

Unusual structural trends in the [MCl3([8]aneSe2)](M = As, Sb, Bi) adducts.

Nicholas J Hill¹, William Levason, Rina Patel, Gillian Reid, Michael Webster.

Abstract

The structures of the homologous [MCl(3)([8]aneSe(2))](M = As, Sb or Bi; [8]aneSe(2)= 1,5-diselenacyclooctane) ladder structures formed from planar M(2)Cl(6) units linked by selenoether ligands with trans Se atoms reveal unexpected structural patterns--possible reasons for these are discussed.

Entities: Chemical

Year: 2004 PMID： 15252675 DOI： 10.1039/b401384k

Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390

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Cited

1 in total

1. Linear Multiselenium Interactions in Dicationic Oligomers of 1,5-(Diselena)canes: Behavior of Se_mc σ(m_c c-n_e e) (6≤m_c ≤16) Elucidated with QTAIM Dual Functional Analysis.

Authors: Satoko Hayashi; Taro Nishide; Kengo Nagata; Waro Nakanishi
Journal: ChemistryOpen Date: 2021-05-02 Impact factor: 2.630

1 in total

Unusual structural trends in the [MCl3([8]aneSe2)](M = As, Sb, Bi) adducts.

1. Linear Multiselenium Interactions in Dicationic Oligomers of 1,5-(Diselena)canes: Behavior of Semc σ(mc c-ne e) (6≤mc ≤16) Elucidated with QTAIM Dual Functional Analysis.

1. Linear Multiselenium Interactions in Dicationic Oligomers of 1,5-(Diselena)canes: Behavior of Se_mc σ(m_c c-n_e e) (6≤m_c ≤16) Elucidated with QTAIM Dual Functional Analysis.