Literature DB >> 15249934

A one-pot synthesis to [(Me3Si)3SiSb]4; a potential precursor for Sb42-.

Felipe García1, Alexander D Hopkins, Richard A Kowenicki, Mary McPartlin, Yolanda Tesa.   

Abstract

The reaction of (Me(3)Si)(3)SiK[middle dot]18-crown-6 with SbCl(3)(3 : 1 equiv.) provides a simple route to the title complex [(Me(3)Si)(3)SiSb](4). The potassium base initially acts as a nucleophile and then as a coupling agent, forming Sb-Sb bonds.

Entities:  

Year:  2004        PMID: 15249934     DOI: 10.1039/B405032K

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  1 in total

1.  Oligosilanylated Antimony Compounds.

Authors:  Rainer Zitz; Karl Gatterer; Crispin R W Reinhold; Thomas Müller; Judith Baumgartner; Christoph Marschner
Journal:  Organometallics       Date:  2015-04-10       Impact factor: 3.876

  1 in total

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