Literature DB >> 15237179

3-Bromomethyl-3-ethyl-3,4,6,7,8,8a-hexahydro-1H-pyrrolo[2,1-c][1,4]oxazine-1,4-dione.

Yun-Yan Kuang1, Ming Huo, Fen-Er Chen.   

Abstract

In the title compound, C10H14BrNO3, the six-membered lactone ring is in a boat conformation, with the two carbonyl groups cis to one another across the boat basal plane. C-H...O hydrogen bonds and weak C-H...Br interactions stabilize the crystal structure.

Entities:  

Year:  2004        PMID: 15237179     DOI: 10.1107/S010827010401131X

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  Synthesis and molecular structure of ethyl [N-tosyl-(R)-prolyloxy]-2(S)-[4-cyano-8,8-ethylenedioxy-5-oxo-5,6,7,8-tetrahydroindolizin-3-yl] acetate, a key intermediate in the total synthesis of (20S)-camptothecins.

Authors:  Yun-Yan Kuang; Fen-Er Chen
Journal:  Molecules       Date:  2007-11-13       Impact factor: 4.411

  1 in total

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