Literature DB >> 15237168

Partially oxidized [2-[(benzoylmethylene)diphenyl-lambda5-phosphino]ethyl]diphenylphosphine as a monohydrate.

E Mothi Mohamed1, Krishnaswamy Panchanatheswaran, John N Low, Christopher Glidewell.   

Abstract

The title compound is a co-crystal of [2-[(benzoylmethylene)diphenyl-lambda5-phosphino]ethyl]diphenylphosphine oxide, [2-[(benzoylmethylene)diphenyl-lambda5-phosphino]ethyl]diphenylphosphine and water in an approximate 2:1:3 ratio, with an overall composition of C34H30O1.678P2.H2O. The ylidic portion shows the expected electronic polarization, and the organic components are linked by a combination of C-H...O and C-H...pi(arene) hydrogen bonds.

Entities:  

Year:  2004        PMID： 15237168     DOI： 10.1107/S0108270104012211

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN： 0108-2701            Impact factor:   1.172


  1 in total

1.  2-(Diphenylphosphinoylmethyl)pyrrole-2-(diphenylphosphinomethyl)pyrrole (0.43/0.57) and tetrachlorido(5-diphenylphosphinomethyl-2H-pyrrole-kappa(2)N,P)titanium(IV).

Authors:  Lewis M Broomfield; Manfred Bochmann; Joseph A Wright
Journal:  Acta Crystallogr C       Date:  2010-02-24       Impact factor: 1.172
  1 in total

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