Literature DB >> 15228293

A new synthesis of pentafluorosulfanylbenzene.

Tatiana A Sergeeva1, William R Dolbier.   

Abstract

[reaction: see text] A new and convenient three-step synthesis of pentafluorosulfanylbenzene from 1,4-cyclohexadiene with an overall yield of >70% is reported along with a number of derivatization reactions.

Entities:  

Year:  2004        PMID： 15228293     DOI： 10.1021/ol0491991

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Discovery of practical production processes for arylsulfur pentafluorides and their higher homologues, bis- and tris(sulfur pentafluorides): Beginning of a new era of "super-trifluoromethyl" arene chemistry and its industry.

Authors:  Teruo Umemoto; Lloyd M Garrick; Norimichi Saito
Journal:  Beilstein J Org Chem       Date:  2012-03-29       Impact factor: 2.883

2.  Pyridine-promoted dediazoniation of aryldiazonium tetrafluoroborates: Application to the synthesis of SF5-substituted phenylboronic esters and iodobenzenes.

Authors:  George Iakobson; Junyi Du; Alexandra M Z Slawin; Petr Beier
Journal:  Beilstein J Org Chem       Date:  2015-08-26       Impact factor: 2.883

3.  A SF5 Derivative of Triphenylphosphine as an Electron-Poor Ligand Precursor for Rh and Ir Complexes.

Authors:  Maria Talavera; Silke Hinze; Thomas Braun; Reik Laubenstein; Roy Herrmann
Journal:  Molecules       Date:  2020-09-01       Impact factor: 4.411

Review 4.  (Hetero)aryl-SVI Fluorides: Synthetic Development and Opportunities.

Authors:  Marc Magre; Shengyang Ni; Josep Cornella
Journal:  Angew Chem Int Ed Engl       Date:  2022-04-27       Impact factor: 16.823
  4 in total

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