Literature DB >> 15228280

Low-valent titanium-mediated cyclopropanation of vinylogous esters.

Nikolai Masalov1, Wei Feng, Jin Kun Cha.   

Abstract

[reaction: see text] Inter- and intramolecular titanium-mediated cyclopropanation reactions of vinylogous esters are reported. Comparison between the Kulinkovich cyclopropanation of esters and vinylogous esters provides mechanistic insight regarding reaction variables such as reaction temperature, solvents, and a Lewis acid additive.

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Year:  2004        PMID: 15228280     DOI: 10.1021/ol0493047

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Olefin Exchange-Mediated Cyclopropanation of Nitriles with Homoallylic Alcohols.

Authors:  Denis N Bobrov; Keunho Kim; Jin Kun Cha
Journal:  Tetrahedron Lett       Date:  2008-06-23       Impact factor: 2.415

2.  Stereochemistry of the Kulinkovich cyclopropanation of nitriles.

Authors:  Dmitry Astashko; Hyung Goo Lee; Denis N Bobrov; Jin K Cha
Journal:  J Org Chem       Date:  2009-08-07       Impact factor: 4.354

  2 in total

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