Literature DB >> 15228274

Generation and synthetic uses of stable 4-[2-isopropylidene]-phenol carbocation from bisphenol A.

Wei-Fu Chen1, Hsing-Yo Lin, Shenghong A Dai.   

Abstract

[reaction: see text] Stable 4-[2-isopropylidene]-phenol carbocation, IPP cation 1, was generated readily by addition of bisphenol A in concentrated sulfuric acid at ambient temperature, and the cation could be used for facile syntheses of 4-isopropenyl phenol (IPP), IPP dimers, and spiro-bisphenol derivatives.

Entities:  

Year:  2004        PMID: 15228274     DOI: 10.1021/ol0493305

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Lewis Acid Catalyzed Transfer Hydromethallylation for the Construction of Quaternary Carbon Centers.

Authors:  Johannes C L Walker; Martin Oestreich
Journal:  Angew Chem Int Ed Engl       Date:  2019-09-12       Impact factor: 15.336

  1 in total

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