Literature DB >> 15227530

Accelerated asymmetric transfer hydrogenation of aromatic ketones in water.

Xiaofeng Wu1, Xiaoguang Li, William Hems, Frank King, Jianliang Xiao.   

Abstract

Asymmetric transfer hydrogenation of various simple aromatic ketones by the Ru-TsDPEN catalyst was shown to be feasible in aqueous HCOONa without calling for any catalyst modification, furnishing ee's of up to 95% and significantly faster rates than in the HCOOH-NEt(3) azeotrope.

Entities:  

Year:  2004        PMID： 15227530     DOI： 10.1039/b403627a

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN： 1477-0520            Impact factor:   3.876


  5 in total

1.  Artificial metalloenzymes based on biotin-avidin technology for the enantioselective reduction of ketones by transfer hydrogenation.

Authors:  Christophe Letondor; Nicolas Humbert; Thomas R Ward
Journal:  Proc Natl Acad Sci U S A       Date:  2005-03-16       Impact factor: 11.205

2.  Chemical and biological studies of nakiterpiosin and nakiterpiosinone.

Authors:  Shuanhu Gao; Qiaoling Wang; Lily Jun-Shen Huang; Lawrence Lum; Chuo Chen
Journal:  J Am Chem Soc       Date:  2010-01-13       Impact factor: 15.419

3.  Synthesis and structure revision of nakiterpiosin.

Authors:  Shuanhu Gao; Qiaoling Wang; Chuo Chen
Journal:  J Am Chem Soc       Date:  2009-02-04       Impact factor: 15.419

Review 4.  Opportunities offered by chiral η⁶-arene/N-arylsulfonyl-diamine-RuII catalysts in the asymmetric transfer hydrogenation of ketones and imines.

Authors:  Jiří Václavík; Petr Kačer; Marek Kuzma; Libor Cervený
Journal:  Molecules       Date:  2011-06-28       Impact factor: 4.411

5.  Room-Temperature Asymmetric Transfer Hydrogenation of Biomass-Derived Levulinic Acid to Optically Pure γ-Valerolactone Using a Ruthenium Catalyst.

Authors:  Vaishali S Shende; Amol B Raut; Prathamesh Raghav; Ashutosh A Kelkar; Bhalchandra M Bhanage
Journal:  ACS Omega       Date:  2019-11-05
  5 in total

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