| Literature DB >> 15225051 |
David A Vicic1, Thomas J Anderson, John A Cowan, Arthur J Schultz.
Abstract
Reaction of two equiv of 1-adamantylzinc bromide with (dippm)NiBr2 (dippm = bis(di-isopropylphosphino)methane) led to a dinuclear metal complex containing a unique linear bridging hydride ligand. The hydride was characterized by neutron diffraction methods, which confirmed a linear bonding mode. Preliminary reactivity studies of this unusual dimer are reported.Entities:
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Year: 2004 PMID： 15225051 DOI： 10.1021/ja047956k
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419