Literature DB >> 15225042

A versatile ruthenium precursor for biphasic catalysis and its application in ionic liquid biphasic transfer hydrogenation: conventional vs task-specific catalysts.

Tilmann J Geldbach1, Paul J Dyson.   

Abstract

The synthesis of a novel imidazolium-tagged ruthenium complex, which represents a versatile precursor for aqueous and ionic liquid biphasic catalysis, is reported. Its utility is demonstrated in the highly enantioselective ionic liquid biphasic transfer hydrogenation of acetophenone and is compared to conventional (untagged) complexes.

Entities:  

Year:  2004        PMID： 15225042     DOI： 10.1021/ja048886k

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  5 in total

Review 1.  Ionic Liquids Beyond Simple Solvents: Glimpses at the State of the Art in Organic Chemistry.

Authors:  Andrea Kuchenbuch; Ralf Giernoth
Journal:  ChemistryOpen       Date:  2015-08-26       Impact factor: 2.911

Review 2.  Charge-tagged ligands: useful tools for immobilising complexes and detecting reaction species during catalysis.

Authors:  Jones Limberger; Bárbara C Leal; Adriano L Monteiro; Jairton Dupont
Journal:  Chem Sci       Date:  2014-08-06       Impact factor: 9.825

Review 3.  Opportunities offered by chiral η⁶-arene/N-arylsulfonyl-diamine-RuII catalysts in the asymmetric transfer hydrogenation of ketones and imines.

Authors:  Jiří Václavík; Petr Kačer; Marek Kuzma; Libor Cervený
Journal:  Molecules       Date:  2011-06-28       Impact factor: 4.411

4.  Metal-conjugated affinity labels: a new concept to create enantioselective artificial metalloenzymes.

Authors:  Thomas Reiner; Dominik Jantke; Alexander N Marziale; Andreas Raba; Jörg Eppinger
Journal:  ChemistryOpen       Date:  2013-02-20       Impact factor: 2.911

5.  Influence of the Ionic Liquid on the Activity of a Supported Ionic Liquid Phase FeII Pincer Catalyst for the Hydrogenation of Aldehydes.

Authors:  Zita Csendes; Julian Brünig; Nevzat Yigit; Günther Rupprechter; Katharina Bica-Schröder; Helmuth Hoffmann; Karl Kirchner
Journal:  Eur J Inorg Chem       Date:  2019-07-29       Impact factor: 2.524
  5 in total

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