| Literature DB >> 15202921 |
Jacques-Alexis Funel1, Joëlle Prunet.
Abstract
The A ring of FR182877, exemplified by ent-4-b,c, has been synthesized, involving an enyne RCM as the key step. A systematic comparison of enyne vs diene RCM for the formation of cyclopentene derivatives showed that the latter metathesis proceeds much more easily even for this ring size.Entities:
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Year: 2004 PMID： 15202921 DOI： 10.1021/jo049557d
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354