| Literature DB >> 15181625 |
Gary J Sharman1, Ian C Jones, Mark P Parnell, Michael C Willis, Mary F Mahon, Dean V Carlson, Antony Williams, Mikhail Elyashberg, Kirill Blinov, Sergey G Molodtsov.
Abstract
The reaction between an alpha,beta-unsaturated pyruvate and ethyl diazoacetate (EDA) yielded two unexpected products. The structures of these products were determined by automated elucidation of the chemical structures using spectroscopic inputs of a series of 1D and 2D NMR data using the computer program ACD/Structure Elucidator, StrucEluc. The formation of these products is rationalised. Their structures were also confirmed by x-ray crystallography. Copyright 2004 John Wiley & Sons, Ltd.Entities:
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Year: 2004 PMID： 15181625 DOI： 10.1002/mrc.1396
Source DB: PubMed Journal: Magn Reson Chem ISSN： 0749-1581 Impact factor: 2.447