Literature DB >> 15176821

Palladium-catalyzed decarboxylation and decarbonylation under hydrothermal conditions: decarboxylative deuteration.

Seijiro Matsubara1, Yutaka Yokota, Koichiro Oshima.   

Abstract

[reaction: see text] Decarboxylation of free carboxylic acid was performed by Pd/C catalyst under hydrothermal water (250 degrees C/4 MPa). Under the hydrothermal conditions of deuterium oxide, decarbonylative deuteration was observed to give fully deuterated hydrocarbons from carboxylic acids or aldehydes.

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Year:  2004        PMID: 15176821     DOI: 10.1021/ol0492602

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  6 in total

1.  Hydrodecarboxylation of Carboxylic and Malonic Acid Derivatives via Organic Photoredox Catalysis: Substrate Scope and Mechanistic Insight.

Authors:  Jeremy D Griffin; Mary A Zeller; David A Nicewicz
Journal:  J Am Chem Soc       Date:  2015-08-28       Impact factor: 15.419

2.  Mild aromatic palladium-catalyzed protodecarboxylation: kinetic assessment of the decarboxylative palladation and the protodepalladation steps.

Authors:  Joshua S Dickstein; John M Curto; Osvaldo Gutierrez; Carol A Mulrooney; Marisa C Kozlowski
Journal:  J Org Chem       Date:  2013-04-29       Impact factor: 4.354

Review 3.  Selective Deoxygenation of Biomass-Derived Bio-oils within Hydrogen-Modest Environments: A Review and New Insights.

Authors:  Kyle A Rogers; Ying Zheng
Journal:  ChemSusChem       Date:  2016-07-07       Impact factor: 8.928

4.  Selectivity Control in the Tandem Aromatization of Bio-Based Furanics Catalyzed by Solid Acids and Palladium.

Authors:  Homer C Genuino; Shanmugam Thiyagarajan; Jan C van der Waal; Ed de Jong; Jacco van Haveren; Daan S van Es; Bert M Weckhuysen; Pieter C A Bruijnincx
Journal:  ChemSusChem       Date:  2016-08-25       Impact factor: 8.928

Review 5.  Trends in the Hydrogen-Deuterium Exchange at the Carbon Centers. Preparation of Internal Standards for Quantitative Analysis by LC-MS.

Authors:  Paulina Grocholska; Remigiusz Bąchor
Journal:  Molecules       Date:  2021-05-18       Impact factor: 4.411

6.  Palladium-Catalyzed Nondirected Late-Stage C-H Deuteration of Arenes.

Authors:  Mirxan Farizyan; Arup Mondal; Sourjya Mal; Fritz Deufel; Manuel van Gemmeren
Journal:  J Am Chem Soc       Date:  2021-09-28       Impact factor: 15.419

  6 in total

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