Literature DB >> 15174842

Isolation and characterization of a carbene derivative of La@C82.

Yutaka Maeda1, Yoichiro Matsunaga, Takatsugu Wakahara, Satomi Takahashi, Takahiro Tsuchiya, Midori O Ishitsuka, Tadashi Hasegawa, Takeshi Akasaka, Michael T H Liu, Kisato Kokura, Ernst Horn, Kenji Yoza, Tatsuhisa Kato, Shingo Okubo, Kaoru Kobayashi, Shigeru Nagase, Kazunori Yamamoto.   

Abstract

The photochemical reaction of La@C82 with 2-adamantane-2,3-[3H]-diazirine affords adduct 2, La@C82(Ad), in a quantitative and highly selective manner. The structure of compound 2 is confirmed by ESR, MS, and UV-vis-NIR spectroscopies, and the first X-ray crystallographic characterization of an endohedral monometallofullerene derivative is reported.

Entities:  

Year:  2004        PMID： 15174842     DOI： 10.1021/ja0316115

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  3 in total

1.  Synthesis of endohedral metallofullerene glycoconjugates by carbene addition.

Authors:  Michio Yamada; Chika I Someya; Tsukasa Nakahodo; Yutaka Maeda; Takahiro Tsuchiya; Takeshi Akasaka
Journal:  Molecules       Date:  2011-11-14       Impact factor: 4.411

2.  Highly regioselective complexation of tungsten with Eu@C82/Eu@C84: interplay between endohedral and exohedral metallic units induced by electron transfer.

Authors:  Lipiao Bao; Pengyuan Yu; Ying Li; Changwang Pan; Wangqiang Shen; Peng Jin; Shuquan Liang; Xing Lu
Journal:  Chem Sci       Date:  2019-04-26       Impact factor: 9.825

3.  Synthesis and characterization of carbene derivatives of Th@C 3v(8)-C82 and U@C 2v(9)-C82: exceptional chemical properties induced by strong actinide-carbon cage interaction.

Authors:  Xinye Liu; Bo Li; Wei Yang; Yang-Rong Yao; Le Yang; Jiaxin Zhuang; Xiaomeng Li; Peng Jin; Ning Chen
Journal:  Chem Sci       Date:  2020-12-21       Impact factor: 9.825
  3 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.