Literature DB >> 15170534

Exact effective force between star-polymers in a Theta-solvent.

M Benhamou1, M Himmi, F Benzouine, A Bettachy, A Derouiche.   

Abstract

We re-examine here the computation of the effective force between two star-polymers of respective numbers of branches f(1) and f(2), immersed in a common Theta-solvent. Such a force originates essentially from the repulsive three-body interactions. To achieve this, we take advantage of some established results using renormalization theory for three-dimensional star-polymers, or conformal invariance for two-dimensional ones. We first show that, in dimension d = 3, the force, F(r), decreases with the center-to-center distance r as F(r)/kappa BT congruent with Af1f2 x [r ln (R2/r2]-1 (r<R), with the exact universal amplitude Af1f2 = f1f2(f1 + f2 - 2)/22. Second, in dimension d = 2, we find that the force decays more slowly as F(r)/kappa BT congruent with Bf1f2 x r-1 (r<R), with the exact universal amplitude Bf1f2. For high distances compared to the gyration radius, R approximately a square root of N, of a single polymer chain at the Theta-point, an exponential decay of the force is expected.

Entities:  

Year:  2004        PMID: 15170534     DOI: 10.1140/epje/i2003-10081-y

Source DB:  PubMed          Journal:  Eur Phys J E Soft Matter        ISSN: 1292-8941            Impact factor:   1.890


  3 in total

1.  Force between unlike star-polymers versus the solvent quality.

Authors:  F Benzouine; M Benhamou; M Himmi
Journal:  Eur Phys J E Soft Matter       Date:  2004-04       Impact factor: 1.890

2.  Exact tricritical exponents for polymers at the FTHETA point in two dimensions.

Authors: 
Journal:  Phys Rev Lett       Date:  1987-08-03       Impact factor: 9.161

3.  Tricritical effect of attractive and repulsive forces on a single polymer coil in a poor solvent.

Authors: 
Journal:  Phys Rev Lett       Date:  1986-05-12       Impact factor: 9.161

  3 in total
  3 in total

1.  Field-theoretical Renormalization-Group approach to critical dynamics of crosslinked polymer blends.

Authors:  M Benhamou; M Chahid
Journal:  Eur Phys J E Soft Matter       Date:  2008-09       Impact factor: 1.890

2.  Theory of microphase separation in charged crosslinked polymer blends with arbitrary charge distribution.

Authors:  A Boussaid; M Benhamou; A El Fazni
Journal:  Eur Phys J E Soft Matter       Date:  2009-12-03       Impact factor: 1.890

3.  Critical microphase properties of crosslinked polymer blends with quenched random impurities.

Authors:  M Benhamou; A Derouiche; A Bettachy; F Elhajjaji
Journal:  Eur Phys J E Soft Matter       Date:  2011-01-10       Impact factor: 1.890

  3 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.