Literature DB >> 15169416

Universal nuclear spin relaxation and long-range order in nematics strongly confined in mass fractal silica gels.

N León1, J-P Korb, I Bonalde, P Levitz.   

Abstract

We show how the low-frequency dependence of the proton spin-lattice relaxation time T1(nu) of octylcyanobiphenyl liquid crystals confined in high-density silica gels evidences a long-range order nematic phase in spite of the strong confinement and random disorder of the gels. The universal value and frequency dependence observed, T1(nu) proportional, variant nu(2/3), is interpreted within a relaxation model due to director fluctuations in nematic liquid crystals confined to mass fractal porous media. The model provides a relation T1(nu) proportional, variant nu(2-d/2), giving a reliable value of the structural fractal dimension d(f)=2.67 for all the host silica gels.

Entities:  

Year:  2004        PMID: 15169416     DOI: 10.1103/PhysRevLett.92.195504

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN: 0031-9007            Impact factor:   9.161


  1 in total

Review 1.  The influence of disorder on thermotropic nematic liquid crystals phase behavior.

Authors:  Vlad Popa-Nita; Ivan Gerlič; Samo Kralj
Journal:  Int J Mol Sci       Date:  2009-09-10       Impact factor: 6.208

  1 in total

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