| Literature DB >> 15169275 |
Abstract
Just as transition rates in a canonical ensemble must respect the principle of detailed balance, constraints exist on transition rates in driven steady states. I derive those constraints, by maximum information-entropy inference, and apply them to the steady states of driven diffusion and a sheared lattice fluid. The resulting ensemble can potentially explain nonequilibrium phase behavior and, for steady shear, gives rise to stress-mediated long-range interactions.Year: 2004 PMID: 15169275 DOI: 10.1103/PhysRevLett.92.150601
Source DB: PubMed Journal: Phys Rev Lett ISSN: 0031-9007 Impact factor: 9.161