Literature DB >> 15154792

Synthesis and structure of heterospin compounds based on the [Mn6(O)2Piv10]-cluster unit and nitroxide.

Victor Ovcharenko1, Elena Fursova, Galina Romanenko, Vladimir Ikorskii.   

Abstract

Reaction of [Mn6(O)2Piv10(Thf)4].Thf with 2,4,4,5,5-pentamethyl-4,5-dihydro-1H-imidazolyl-3-oxide-1-oxyl (NIT-Me) produces different heterospin compounds depending of the solvent used in the synthesis. Among the latter a new molecular magnet [Mn6(O)2Piv10(Thf)2(NIT-Me)Mn6(O)2Piv10(Thf)(CH2Cl2)(NIT-Me)] with Tc = 3.5 K has been found.

Entities:  

Year:  2004        PMID： 15154792     DOI： 10.1021/ic049859y

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  2 in total

1.  Synthesis and Structural Characterization of a Metal Cluster and a Coordination Polymer Based on the [Mn(6)(mu(4)-O)(2)] Unit.

Authors:  Eleni E Moushi; Anastasios J Tasiopoulos; Manolis J Manos
Journal:  Bioinorg Chem Appl       Date:  2010-06-07       Impact factor: 7.778

2.  'Metal Complexes as Ligands' for the Synthesis of Coordination Polymers: A MnIII Monomer as a Building Block for the Preparation of an Unprecedented 1-D {MnIIMnIII}n Linear Chain.

Authors:  Konstantinos N Pantelis; Georgios Karotsis; Christos Lampropoulos; Luís Cunha-Silva; Albert Escuer; Theocharis C Stamatatos
Journal:  Materials (Basel)       Date:  2020-03-17       Impact factor: 3.623
  2 in total

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