Literature DB >> 15154791

Supramolecular stereocontrol of octahedral metal-centered chirality. Ligand modulation.

Jonathan J Jodry1, Richard Frantz, Jérôme Lacour.   

Abstract

By associating chiral labile [FeL3](2+) complexes with TRISPHAT anions, a stereocontrol of the metal-centered chirality is feasible; the sense of the stereoselective induction and its magnitude strongly depends upon the structure of the diimine ligands (L: bpy, phen).

Entities:  

Year:  2004        PMID: 15154791     DOI: 10.1021/ic049661d

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  2 in total

1.  Chiral control of spin-crossover dynamics in Fe(II) complexes.

Authors:  Malte Oppermann; Francesco Zinna; Jérôme Lacour; Majed Chergui
Journal:  Nat Chem       Date:  2022-05-26       Impact factor: 24.427

2.  Acetylene Derivatives of Cationic Diazaoxatriangulenes and Diaza [4]Helicenes - Access to Red Emitters and Planar Chiral Stereochemical Traits.

Authors:  Pavol Ondrisek; Margaux Elie; Marion Pupier; Adiran de Aguirre; Amalia I Poblador-Bahamonde; Céline Besnard; Jérôme Lacour
Journal:  Chemistry       Date:  2022-02-09       Impact factor: 5.020

  2 in total

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