| Literature DB >> 15149206 |
Curtis P Berlinguette1, Alina Dragulescu-Andrasi, Andreas Sieber, José Ramón Galán-Mascarós, Hans-Ulrich Güdel, Catalina Achim, Kim R Dunbar.
Abstract
A charge-transfer-induced spin transition (CTIST) is observed in the discrete cyanide-bridged complex, {[Co(tmphen)2]3[Fe(CN)6]2}. Single-crystal X-ray diffraction, 57Fe Mössbauer spectroscopy, and magnetic susceptibility were used collectively to describe the oxidation states of the Co and Fe ions in this cluster as a function of temperature. This pentanuclear complex represents the first example of a CTIST at the discrete molecular level.Entities:
Year: 2004 PMID： 15149206 DOI： 10.1021/ja039451k
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419