Literature DB >> 15116178

Ferromagnetic NiII-GdIII interactions in complexes with NiGd, NiGdNi, and NiGdGdNi cores supported by tripodal ligands.

Tomoka Yamaguchi1, Yukinari Sunatsuki, Masaaki Kojima, Haruo Akashi, Masanobu Tsuchimoto, Nazzareno Re, Shutaro Osa, Naohide Matsumoto.   

Abstract

Dinuclear [(NiL)Gd(hfac)(2)(EtOH)](H(3)L = 1,1,1-tris(N-salicylideneaminomethyl)ethane, Hhfac = hexafluoroacetylacetone), trinuclear [(NiL)(2)Gd(NO(3))], and tetranuclear [(NiL)Gd(CH(3)CO(2))(2)(MeOH)](2) complexes, were prepared by treating [Ni(HL)] with [Gd(hfac)(3)(H(2)O)(2)], Gd(NO(3))(3).6H(2)O, and Gd(CH(3)CO(2))(3).4H(2)O, respectively, in the presence of Et(3)N. All the complexes show that ferromagnetic interactions occur between the Ni(II) and Gd(III) ions.

Entities:  

Year:  2004        PMID: 15116178     DOI: 10.1039/b401033g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Trinuclear NiII-LnIII-NiII Complexes with Schiff Base Ligands: Synthesis, Structure, and Magnetic Properties.

Authors:  Anastasia N Georgopoulou; Michael Pissas; Vassilis Psycharis; Yiannis Sanakis; Catherine P Raptopoulou
Journal:  Molecules       Date:  2020-05-12       Impact factor: 4.411

2.  Crystal structures of {1,1,1-tris-[(salicylaldimino)-meth-yl]ethane}-gallium as both a pyridine solvate and an aceto-nitrile 0.75-solvate and {1,1,1-tris[(salicylaldimino)-meth-yl]ethane}-indium di-chloro-methane solvate.

Authors:  Dominic L Ventura; William W Brennessel; William S Durfee
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2020-04-03
  2 in total

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