Literature DB >> 15113191

Selectivity control of carbonylation of methanol to dimethyl oxalate and dimethyl carbonate over gold anode by electrochemical potential.

Akiyasu Funakawa1, Ichiro Yamanaka, Sakae Takenaka, Kiyoshi Otsuka.   

Abstract

New and unique electrocatalysis of gold for the carbonylation of methanol to dimethyl oxalate (DMO) and dimethyl carbonate (DMC) was found. The selectivity to DMO and DMC could be controlled over gold anode by electrochemical potential, as you like. Drastic changes of gold electrocatalysis was due to changes of the oxidation state of gold, Au0 or Au3+.

Entities:  

Year:  2004        PMID： 15113191     DOI： 10.1021/ja0395700

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  3 in total

1.  The promoting effect of adsorbed carbon monoxide on the oxidation of alcohols on a gold catalyst.

Authors:  Paramaconi Rodriguez; Youngkook Kwon; Marc T M Koper
Journal:  Nat Chem       Date:  2011-12-11       Impact factor: 24.427

2.  Dopant-tuned stabilization of intermediates promotes electrosynthesis of valuable C3 products.

Authors:  Tao-Tao Zhuang; Dae-Hyun Nam; Ziyun Wang; Hui-Hui Li; Christine M Gabardo; Yi Li; Zhi-Qin Liang; Jun Li; Xiao-Jing Liu; Bin Chen; Wan Ru Leow; Rui Wu; Xue Wang; Fengwang Li; Yanwei Lum; Joshua Wicks; Colin P O'Brien; Tao Peng; Alexander H Ip; Tsun-Kong Sham; Shu-Hong Yu; David Sinton; Edward H Sargent
Journal:  Nat Commun       Date:  2019-10-22       Impact factor: 14.919

Review 3.  Determination and perturbation of the electronic potentials of solid catalysts for innovative catalysis.

Authors:  Xingyu Qi; Tatsuya Shinagawa; Fuminao Kishimoto; Kazuhiro Takanabe
Journal:  Chem Sci       Date:  2020-12-08       Impact factor: 9.825
  3 in total

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