| Literature DB >> 15070351 |
Tullio Caronna1, Rosalba Liantonio, Thomas A Logothetis, Pierangelo Metrangolo, Tullio Pilati, Giuseppe Resnati.
Abstract
The halogen bonding and the pi...pi stacking interactions induce the noncovalent self-assembly of modules into photoreactive supramolecular architecture. The pi...pi interaction pre-organizes the template, and the halogen bonding aligns the olefins to conform to the topochemical principle for photoreaction. The UV irradiation of the crystal resulted in a cyclization product with quantitative yield and stereospecificity.Entities:
Year: 2004 PMID: 15070351 DOI: 10.1021/ja039884n
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419