Literature DB >> 15070323

Rhodium-catalyzed imination of sulfoxides and sulfides: efficient preparation of N-unsubstituted sulfoximines and sulfilimines.

Hiroaki Okamura1, Carsten Bolm.   

Abstract

The Rh(II)-catalyzed imination of sulfoxides and sulfides using [Rh(2)(OAc)(4)] as a catalyst and trifluoroacetamide or sulfonylamides in combination with iodobenzene diacetate and magnesium oxide affords sulfoximines and sulfilimines, respectively, in a stereospecific manner. [reaction: see text]

Entities:  

Year:  2004        PMID： 15070323     DOI： 10.1021/ol049715n

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  19 in total

1.  Intramolecular Fe(II)-catalyzed N-O or N-N bond formation from aryl azides.

Authors:  Benjamin J Stokes; Carl V Vogel; Linda K Urnezis; Minjie Pan; Tom G Driver
Journal:  Org Lett       Date:  2010-06-18       Impact factor: 6.005

Review 2.  Chemistry of polyvalent iodine.

Authors:  Viktor V Zhdankin; Peter J Stang
Journal:  Chem Rev       Date:  2008-12       Impact factor: 60.622

Review 3.  Synthesis and Transformations of NH-Sulfoximines.

Authors:  Michael Andresini; Arianna Tota; Leonardo Degennaro; James A Bull; Renzo Luisi
Journal:  Chemistry       Date:  2021-10-13       Impact factor: 5.020

4.  Stereospecific α-(hetero)arylation of sulfoximines and sulfonimidamides.

Authors:  Zachary P Shultz; Thomas Scattolin; Lukasz Wojtas; Justin M Lopchuk
Journal:  Nat Synth       Date:  2022-01-31

5.  Novel Pieces for the Emerging Picture of Sulfoximines in Drug Discovery: Synthesis and Evaluation of Sulfoximine Analogues of Marketed Drugs and Advanced Clinical Candidates.

Authors:  Juan Alberto Sirvent; Ulrich Lücking
Journal:  ChemMedChem       Date:  2017-03-22       Impact factor: 3.466

6.  Catalytic Enantioselective Synthesis of Pyridyl Sulfoximines.

Authors:  Yu Tang; Scott J Miller
Journal:  J Am Chem Soc       Date:  2021-06-14       Impact factor: 16.383

7.  The use of chiral lithium amides in the desymmetrisation of N-trialkylsilyl dimethyl sulfoximines.

Authors:  Matthew J McGrath; Carsten Bolm
Journal:  Beilstein J Org Chem       Date:  2007-10-16       Impact factor: 2.883

8.  Transfer of Electrophilic NH Using Convenient Sources of Ammonia: Direct Synthesis of NH Sulfoximines from Sulfoxides.

Authors:  Marina Zenzola; Robert Doran; Leonardo Degennaro; Renzo Luisi; James A Bull
Journal:  Angew Chem Int Ed Engl       Date:  2016-04-29       Impact factor: 15.336

9.  Identification of Atuveciclib (BAY 1143572), the First Highly Selective, Clinical PTEFb/CDK9 Inhibitor for the Treatment of Cancer.

Authors:  Ulrich Lücking; Arne Scholz; Philip Lienau; Gerhard Siemeister; Dirk Kosemund; Rolf Bohlmann; Hans Briem; Ildiko Terebesi; Kirstin Meyer; Katja Prelle; Karsten Denner; Ulf Bömer; Martina Schäfer; Knut Eis; Ray Valencia; Stuart Ince; Franz von Nussbaum; Dominik Mumberg; Karl Ziegelbauer; Bert Klebl; Axel Choidas; Peter Nussbaumer; Matthias Baumann; Carsten Schultz-Fademrecht; Gerd Rühter; Jan Eickhoff; Michael Brands
Journal:  ChemMedChem       Date:  2017-10-16       Impact factor: 3.466

10.  Sulfoximines-Assisted Rh(III)-Catalyzed C-H Activation and Intramolecular Annulation for the Synthesis of Fused Isochromeno-1,2-Benzothiazines Scaffolds under Room Temperature.

Authors:  Bao Wang; Xu Han; Jian Li; Chunpu Li; Hong Liu
Journal:  Molecules       Date:  2020-05-28       Impact factor: 4.411
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