Literature DB >> 15070298

Selective selenocatalytic allylic chlorination.

Jon A Tunge1, Shelli R Mellegaard.   

Abstract

Ene-chlorination of olefins by N-chlorosuccinimide is catalyzed by phenylselenenyl chloride. This reaction demonstrates the catalytic conversion of C-H bonds into more reactive C-Cl bonds. [reaction: see text]

Entities:  

Year:  2004        PMID： 15070298     DOI： 10.1021/ol036525o

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  6 in total

1.  A New Alkylation-Elimination Method for Synthesis of Antiviral Fluoromethylenecyclopropane Analogues of Nucleosides.

Authors:  Shaoman Zhou; Jiri Zemlicka
Journal:  Tetrahedron       Date:  2005-07-25       Impact factor: 2.457

2.  Catalytic, stereospecific syn-dichlorination of alkenes.

Authors:  Alexander J Cresswell; Stanley T-C Eey; Scott E Denmark
Journal:  Nat Chem       Date:  2015-01-12       Impact factor: 24.427

3.  Regiocontrolled allylic functionalization of internal alkene via selenium-π-acid catalysis guided by boron substitution.

Authors:  Ling Yang; Yuan Liu; Wen-Xin Fan; Dong-Hang Tan; Qingjiang Li; Honggen Wang
Journal:  Chem Sci       Date:  2022-04-22       Impact factor: 9.969

4.  Scalable, enantioselective synthesis of germacrenes and related sesquiterpenes inspired by terpene cyclase phase logic.

Authors:  Klement Foo; Ippei Usui; Daniel C G Götz; Erik W Werner; Dane Holte; Phil S Baran
Journal:  Angew Chem Int Ed Engl       Date:  2012-10-12       Impact factor: 15.336

5.  Copper(I)-catalysed site-selective C(sp3)-H bond chlorination of ketones, (E)-enones and alkylbenzenes by dichloramine-T.

Authors:  Jianwen Jin; Yichao Zhao; Sara Helen Kyne; Kaveh Farshadfar; Alireza Ariafard; Philip Wai Hong Chan
Journal:  Nat Commun       Date:  2021-07-01       Impact factor: 14.919

6.  Selenophosphoramide-catalyzed diamination and oxyamination of alkenes.

Authors:  John R Tabor; Derek C Obenschain; Forrest E Michael
Journal:  Chem Sci       Date:  2019-12-26       Impact factor: 9.825
  6 in total

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