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Literature DB >> 15069515

Absolute asymmetric synthesis by nucleophilic carbonyl addition using chiral crystals of achiral amides.

Abstract

Reaction of the chiral crystals of the achiral amides with n-butyllithium in toluene at -80 degrees C gave optically active alcohols in 17-84% ee.

Entities: Chemical

Year: 2004 PMID： 15069515 DOI： 10.1039/b315729f

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Authors: Adel Hamada; Yamina Boudinar; Adel Beghidja; Mehdi Boutebdja
Journal: Acta Crystallogr Sect E Struct Rep Online Date: 2012-08-15

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