Literature DB >> 15053593

Transition-metal-free: a highly efficient catalytic aerobic alcohol oxidation process.

Renhua Liu1, Xinmiao Liang, Chunyan Dong, Xinquan Hu.   

Abstract

A highly efficient catalytic system without transition metals has been developed for aerobic alcohol oxidations. Under the optimal reaction conditions, various alcohol substrates were converted into their corresponding carbonyl compounds by air with TEMPO/Br2/NaNO2 as catalyst, especially the oxidation of benzylic alcohols to benzaldehydes in high yields.

Entities:  

Year:  2004        PMID: 15053593     DOI: 10.1021/ja031765k

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  17 in total

1.  Aminoxyl-Catalyzed Electrochemical Diazidation of Alkenes Mediated by a Metastable Charge-Transfer Complex.

Authors:  Juno C Siu; Joseph B Parry; Song Lin
Journal:  J Am Chem Soc       Date:  2019-01-28       Impact factor: 15.419

2.  KetoABNO/NOx Cocatalytic Aerobic Oxidation of Aldehydes to Carboxylic Acids and Access to α-Chiral Carboxylic Acids via Sequential Asymmetric Hydroformylation/Oxidation.

Authors:  Kelsey C Miles; M Leigh Abrams; Clark R Landis; Shannon S Stahl
Journal:  Org Lett       Date:  2016-07-13       Impact factor: 6.005

3.  Redox-Neutral TEMPO Catalysis: Direct Radical (Hetero)Aryl C-H Di- and Trifluoromethoxylation.

Authors:  Johnny W Lee; Sanghyun Lim; Daniel N Maienshein; Peng Liu; Ming-Yu Ngai
Journal:  Angew Chem Int Ed Engl       Date:  2020-09-24       Impact factor: 15.336

4.  Nitrate as a Redox Co-Catalyst for the Aerobic Pd-Catalyzed Oxidation of Unactivated sp(3)-C-H Bonds.

Authors:  Kara J Stowers; Asako Kubota; Melanie S Sanford
Journal:  Chem Sci       Date:  2012-08-30       Impact factor: 9.825

5.  Highly efficient Cu(I)-catalyzed oxidation of alcohols to ketones and aldehydes with diaziridinone.

Authors:  Yingguang Zhu; Baoguo Zhao; Yian Shi
Journal:  Org Lett       Date:  2013-02-15       Impact factor: 6.005

Review 6.  Practical aerobic oxidations of alcohols and amines with homogeneous copper/TEMPO and related catalyst systems.

Authors:  Bradford L Ryland; Shannon S Stahl
Journal:  Angew Chem Int Ed Engl       Date:  2014-07-07       Impact factor: 15.336

7.  High-Potential Electrocatalytic O2 Reduction with Nitroxyl/NO x Mediators: Implications for Fuel Cells and Aerobic Oxidation Catalysis.

Authors:  James B Gerken; Shannon S Stahl
Journal:  ACS Cent Sci       Date:  2015-07-15       Impact factor: 14.553

8.  Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water.

Authors:  Shi-Juan Liu; Miao Zhang; Rong Lu; Xiu-Ying Li; Guang-Bo Che
Journal:  Molecules       Date:  2018-07-27       Impact factor: 4.411

9.  Oxoammonium salts are catalysing efficient and selective halogenation of olefins, alkynes and aromatics.

Authors:  Weijin Wang; Xinyao Li; Xiaoxue Yang; Lingsheng Ai; Zhiwen Gong; Ning Jiao; Song Song
Journal:  Nat Commun       Date:  2021-06-23       Impact factor: 14.919

10.  Transition-Metal-Free Oxidative Cross-Coupling of Tetraarylborates to Biaryls Using Organic Oxidants.

Authors:  Carolin Gerleve; Armido Studer
Journal:  Angew Chem Int Ed Engl       Date:  2020-04-24       Impact factor: 15.336

View more

北京卡尤迪生物科技股份有限公司 © 2022-2023.