| Literature DB >> 15053573 |
Stéphane Rigaut1, Karine Costuas, Daniel Touchard, Jean-Yves Saillard, Stéphane Golhen, Pierre H Dixneuf.
Abstract
We report the preparation of the first real bis(allenylidene) metal complex trans-[Ph2C=C=C=Ru=C=C=CPh2(dppe)2]2+, and its one electron reduction that gives a stable radical with the unpaired electron delocalized over both trans carbon-rich chains linked by the ruthenium atom, on the basis of spectroscopic and DFT, QM(DFT)/MM computational studies.Entities:
Year: 2004 PMID： 15053573 DOI： 10.1021/ja049631+
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419