Literature DB >> 15049667

Halide-free dehydrative allylation using allylic alcohols promoted by a palladium-triphenyl phosphite catalyst.

Yoshihito Kayaki1, Takashi Koda, Takao Ikariya.   

Abstract

The triphenyl phosphite-palladium complex was found to effect catalytic substitution reactions of allylic alcohols via a direct C-O bond cleavage. The dehydrative etherification proceeded efficiently without any cocatalysts and bases to give allylic ethers in good to excellent yields.

Entities:  

Year:  2004        PMID： 15049667     DOI： 10.1021/jo030370g

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  7 in total

1.  Gold(I)-catalyzed amination of allylic alcohols with cyclic ureas and related nucleophiles.

Authors:  Paramita Mukherjee; Ross A Widenhoefer
Journal:  Org Lett       Date:  2010-03-19       Impact factor: 6.005

2.  Gold(I)-catalyzed intramolecular amination of allylic alcohols with alkylamines.

Authors:  Paramita Mukherjee; Ross A Widenhoefer
Journal:  Org Lett       Date:  2011-02-11       Impact factor: 6.005

3.  Homogeneous pd-catalyzed enantioselective decarboxylative protonation.

Authors:  Smaranda C Marinescu; Toyoki Nishimata; Justin T Mohr; Brian M Stoltz
Journal:  Org Lett       Date:  2008-02-28       Impact factor: 6.005

4.  Boron-catalyzed dehydrative allylation of 1,3-diketones and β-ketone esters with 1,3-diarylallyl alcohols in water.

Authors:  Guo-Min Zhang; Hua Zhang; Bei Wang; Ji-Yu Wang
Journal:  RSC Adv       Date:  2021-05-10       Impact factor: 4.036

5.  Equilibrium Study of Pd(dba)2 and P(OPh)3 in the Pd-Catalyzed Allylation of Aniline by Allyl Alcohol.

Authors:  Supaporn Sawadjoon; Andreas Orthaber; Per J R Sjöberg; Lars Eriksson; Joseph S M Samec
Journal:  Organometallics       Date:  2013-12-31       Impact factor: 3.876

6.  Activation of alcohols with carbon dioxide: intermolecular allylation of weakly acidic pronucleophiles.

Authors:  Simon B Lang; Theresa M Locascio; Jon A Tunge
Journal:  Org Lett       Date:  2014-08-04       Impact factor: 6.005

7.  Cross-Coupling Synthesis of Methylallyl Alkenes: Scope Extension and Mechanistic Study.

Authors:  Clémence Tabélé; Christophe Curti; Youssef Kabri; Nicolas Primas; Patrice Vanelle
Journal:  Molecules       Date:  2015-12-21       Impact factor: 4.411
  7 in total

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