Literature DB >> 15049640

Paired electrosynthesis of cyanoacetic acid.

Belen Batanero1, Fructuoso Barba, Carlos M Sánchez-Sánchez, Antonio Aldaz.   

Abstract

Cyanoacetic acid is formed by cathodic reduction of CO(2) and anodic oxidation of the tetraalkylammonium salt anion; the process is conduced in acetonitrile using a divided cell with a medium porosity glass-frit diaphragm. A mechanism for this paired electrochemical reaction is proposed.

Entities:  

Year:  2004        PMID： 15049640     DOI： 10.1021/jo0358473

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  3 in total

1.  Synthetic Organic Electrochemical Methods Since 2000: On the Verge of a Renaissance.

Authors:  Ming Yan; Yu Kawamata; Phil S Baran
Journal:  Chem Rev       Date:  2017-10-09       Impact factor: 60.622

Review 2.  Electrocarboxylation: towards sustainable and efficient synthesis of valuable carboxylic acids.

Authors:  Roman Matthessen; Jan Fransaer; Koen Binnemans; Dirk E De Vos
Journal:  Beilstein J Org Chem       Date:  2014-10-27       Impact factor: 2.883

3.  General technoeconomic analysis for electrochemical coproduction coupling carbon dioxide reduction with organic oxidation.

Authors:  Jonggeol Na; Bora Seo; Jeongnam Kim; Chan Woo Lee; Hyunjoo Lee; Yun Jeong Hwang; Byoung Koun Min; Dong Ki Lee; Hyung-Suk Oh; Ung Lee
Journal:  Nat Commun       Date:  2019-11-15       Impact factor: 14.919
  3 in total

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