Literature DB >> 15049618

2,5-Dialkyl cyclohexenones by Fe(CO)5-mediated carbonylation of alkenyl cyclopropanes: functional group compatibility.

Douglass F Taber1, Pramod V Joshi, Kazuo Kanai.   

Abstract

The preparation of alkenyl cyclopropanes 1 with a variety of common organic functionalities is reported. These substrates were subjected to the Fe(CO)(5)-mediated carbonylation process under a CO atmosphere, leading to the formation of 2,5-disubstituted cyclohexenones 2, important intermediates for target-directed synthesis.

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Year:  2004        PMID： 15049618     DOI： 10.1021/jo0302760

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  7 in total

1.  Recent Applications of Acyclic (Diene)iron Complexes and (Dienyl)iron Cations in Organic Synthesis.

Authors:  William A Donaldson; Subhabrata Chaudhury
Journal:  European J Org Chem       Date:  2009-08

2.  Mechanism and Reactivity of Rh-Catalyzed Intermolecular [5+1] Cycloaddition of 3-Acyloxy-1,4-Enyne (ACE) and CO: A Computational Study.

Authors:  Xiao-Na Ke; Casi M Schienebeck; Chen-Chen Zhou; Xiufang Xu; Weiping Tang
Journal:  Chin Chem Lett       Date:  2015-03-27       Impact factor: 6.779

3.  Intramolecular [1 + 4 + 1] cycloaddition: establishment of the method.

Authors:  Douglass F Taber; Pengfei Guo; Na Guo
Journal:  J Am Chem Soc       Date:  2010-08-18       Impact factor: 15.419

4.  Synthesis of (+)-coronafacic acid.

Authors:  Douglass F Taber; Ritesh B Sheth; Weiwei Tian
Journal:  J Org Chem       Date:  2009-03-20       Impact factor: 4.354

5.  A three-step route to a tricyclic steroid precursor.

Authors:  Douglass F Taber; Ritesh B Sheth
Journal:  J Org Chem       Date:  2008-09-25       Impact factor: 4.354

6.  Catalytic [5 + 1]-Cycloadditions of Vinylcyclopropanes and Vinylidenes.

Authors:  Conner M Farley; Kohei Sasakura; You-Yun Zhou; Vibha V Kanale; Christopher Uyeda
Journal:  J Am Chem Soc       Date:  2020-02-27       Impact factor: 15.419

7.  Transition Metal-Catalyzed Selective Carbon-Carbon Bond Cleavage of Vinylcyclopropanes in Cycloaddition Reactions.

Authors:  Jianhua Wang; Stephanie A Blaszczyk; Xiaoxun Li; Weiping Tang
Journal:  Chem Rev       Date:  2020-08-05       Impact factor: 72.087
  7 in total

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