Literature DB >> 15038695

Enantioselective guest binding and dynamic resolution of cationic ruthenium complexes by a chiral metal-ligand assembly.

Dorothea Fiedler1, Dennis H Leung, Robert G Bergman, Kenneth N Raymond.   

Abstract

A supramolecular metal-ligand assembly encapsulates a variety of cationic half-sandwich ruthenium complexes. Due to the chirality of both host and guest, chiral recognition is observed with diastereomeric excesses up to 70%. The chiral cavity can be used to carry out a dynamic resolution of the rapidly equilibrating enantiomers of the chiral organometallic guest.

Entities:  

Year:  2004        PMID： 15038695     DOI： 10.1021/ja039225a

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  9 in total

Review 1.  Supramolecular coordination: self-assembly of finite two- and three-dimensional ensembles.

Authors:  Rajesh Chakrabarty; Partha Sarathi Mukherjee; Peter J Stang
Journal:  Chem Rev       Date:  2011-08-24       Impact factor: 60.622

2.  Enantioseparation in Hierarchically Porous Assemblies of Homochiral Cages.

Authors:  Chengfeng Zhu; Keke Yang; Hongzhao Wang; Yu Fang; Liang Feng; Jiaqi Zhang; Zhifeng Xiao; Xiang Wu; Yougui Li; Yanming Fu; Wencheng Zhang; Kun-Yu Wang; Hong-Cai Zhou
Journal:  ACS Cent Sci       Date:  2022-04-22       Impact factor: 18.728

3.  Water-soluble macrocycles synthesized via the weak-link approach.

Authors:  Michael J Wiester; Chad A Mirkin
Journal:  Inorg Chem       Date:  2009-09-07       Impact factor: 5.165

4.  From solvolysis to self-assembly.

Authors:  Peter J Stang
Journal:  J Org Chem       Date:  2009-01-02       Impact factor: 4.354

5.  Water-mediated deracemization of a bisporphyrin helicate assisted by diastereoselective encapsulation of chiral guests.

Authors:  Naoki Ousaka; Shinya Yamamoto; Hiroki Iida; Takuya Iwata; Shingo Ito; Yuh Hijikata; Stephan Irle; Eiji Yashima
Journal:  Nat Commun       Date:  2019-03-29       Impact factor: 14.919

6.  Solvent Drives Switching between Λ and Δ Metal Center Stereochemistry of M8L6 Cubic Cages.

Authors:  Weichao Xue; Tanya K Ronson; Zifei Lu; Jonathan R Nitschke
Journal:  J Am Chem Soc       Date:  2022-04-01       Impact factor: 16.383

7.  Homochiral D4-symmetric metal-organic cages from stereogenic Ru(II) metalloligands for effective enantioseparation of atropisomeric molecules.

Authors:  Kai Wu; Kang Li; Ya-Jun Hou; Mei Pan; Lu-Yin Zhang; Ling Chen; Cheng-Yong Su
Journal:  Nat Commun       Date:  2016-02-03       Impact factor: 14.919

8.  Quantification of Stereochemical Communication in Metal-Organic Assemblies.

Authors:  Ana M Castilla; Mark A Miller; Jonathan R Nitschke; Maarten M J Smulders
Journal:  Angew Chem Weinheim Bergstr Ger       Date:  2016-06-02

9.  Quantification of Stereochemical Communication in Metal-Organic Assemblies.

Authors:  Ana M Castilla; Mark A Miller; Jonathan R Nitschke; Maarten M J Smulders
Journal:  Angew Chem Int Ed Engl       Date:  2016-06-02       Impact factor: 15.336
  9 in total

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