Literature DB >> 15015116

Heterogeneous dynamics at the glass transition in van der Waals liquids: determination of the characteristic scale.

S Merabia1, D Long.   

Abstract

Recent experiments have demonstrated that the dynamics in liquids close to the glass transition temperature is strongly heterogeneous. The characteristic size of these heterogeneities has been measured to be a few nanometers at Tg. We extend here a recent model for describing the heterogeneous nature of the dynamics which allows both to derive this length scale and the right orders of magnitude of the heterogeneities of the dynamics close to the glass transition. Our model allows then to interpret quantitatively small probes diffusion experiments.

Year:  2002        PMID: 15015116     DOI: 10.1140/epje/i2002-10084-2

Source DB:  PubMed          Journal:  Eur Phys J E Soft Matter        ISSN: 1292-8941            Impact factor:   1.890


  4 in total

1.  Heterogeneous nature of the dynamics and glass transition in thin polymer films.

Authors:  S Merabia; P Sotta; D Long
Journal:  Eur Phys J E Soft Matter       Date:  2004-10       Impact factor: 1.890

2.  Mechanical properties of thin confined polymer films close to the glass transition in the linear regime of deformation: theory and simulations.

Authors:  A Dequidt; D R Long; P Sotta; O Sanséau
Journal:  Eur Phys J E Soft Matter       Date:  2012-07-19       Impact factor: 1.890

3.  Dynamical heterogeneities and mechanical non-linearities: Modeling the onset of plasticity in polymer in the glass transition.

Authors:  R J Masurel; P Gelineau; F Lequeux; S Cantournet; H Montes
Journal:  Eur Phys J E Soft Matter       Date:  2017-12-27       Impact factor: 1.890

4.  Can the glass transition in bulk polymers be modeled by percolation picture?

Authors:  Yaşar Yilmaz; Demet Kaya; Onder Pekcan
Journal:  Eur Phys J E Soft Matter       Date:  2004-09       Impact factor: 1.890

  4 in total

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