Literature DB >> 15010798

A novel mixed-valence complex containing Co(II)(2)Co(III)(2) molecular squares with 4,5-imidazoledicarboxylate bridges.

Chuan-Feng Wang1, En-Qing Gao, Zheng He, Chun-Hua Yan.   

Abstract

A heterometallic complex, Na(2)[Co(II)(2)Co(III)(2)(IDC(3-))(4)(bipy)(4)].12H(2)O (bipy = 2,2'-bipyridine), in which mixed-valence tetranuclear squares with imidazoledicarboxylate (IDC(3-)) linkers are tethered into a unique chain through disodium units, is hydrothermally synthesized and structurally and magnetically characterized.

Entities:  

Year:  2004        PMID: 15010798     DOI: 10.1039/b315357f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Diaqua-bis(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-κN,O)magnesium(II) 3.5-hydrate.

Authors:  Xiang-Yun Liu; Li-Hua Liu
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-02-17
  1 in total

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