Literature DB >> 15010791

Exploration of the pentacyano-cyclo-pentadienide ion, C(5)(CN)(5)(-), as a weakly coordinating anion and potential superacid conjugate base. Silylation and protonation.

Christopher Richardson1, Christopher A Reed.   

Abstract

The reportedly unprotonatable pentacyano-cyclo-pentadienide ion, C(5)(CN)(5)(-), can be protonated and silylated at the cyano N atom using electrophilic reagents derived from weakly coordinating carborane anions.

Entities:  

Year:  2004        PMID： 15010791     DOI： 10.1039/b316122f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  A Scalable, One-Pot Synthesis of 1,2,3,4,5-Pentacarbomethoxycyclopentadiene.

Authors:  M Alex Radtke; Caroline C Dudley; Jacob M O'Leary; Tristan H Lambert
Journal:  Synthesis (Stuttg)       Date:  2019-03       Impact factor: 3.157

2.  Silylated cyclopentadienes as competent silicon Lewis acid catalysts.

Authors:  M Alex Radtke; Tristan H Lambert
Journal:  Chem Sci       Date:  2018-06-29       Impact factor: 9.825

3.  Ion-pairing π-electronic systems: ordered arrangement and noncovalent interactions of negatively charged porphyrins.

Authors:  Yoshifumi Sasano; Hiroki Tanaka; Yohei Haketa; Yoichi Kobayashi; Yukihide Ishibashi; Tatsuki Morimoto; Ryuma Sato; Yasuteru Shigeta; Nobuhiro Yasuda; Tsuyoshi Asahi; Hiromitsu Maeda
Journal:  Chem Sci       Date:  2021-06-14       Impact factor: 9.825
  3 in total

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