| Literature DB >> 1499023 |
H Redlich1, W Sudau, A K Szardenings, R Vollerthun.
Abstract
7-Deoxy-7-iodohept-1-enitols react intramolecularly to give 5-carba analogues of pyranoses (pseudo sugars) by the action of tributyltin hydride, which generates a radical at C-7. The configuration at the new chiral centre depends on the relative orientation of the oxygen functions in the starting material and the pattern of substitution.Entities:
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Year: 1992 PMID： 1499023 DOI： 10.1016/0008-6215(92)84055-w
Source DB: PubMed Journal: Carbohydr Res ISSN： 0008-6215 Impact factor: 2.104