Literature DB >> 14986972

Catalytic allylic oxidation with a recyclable, fluorous seleninic acid.

David Crich1, Yekui Zou.   

Abstract

In conjunction with iodoxybenzene as reoxidant perfluorooctylseleninic acid catalyzes the allylic oxidation of alkenes to enones in trifluoromethylbenzene at reflux in moderate to good yield. After a reductive workup with sodium metabisulfite, the catalyst is recovered by fluorous extraction in the form of bis(perfluorooctyl) diselenide, which, itself, serves as a convenient catalyst precursor. [reaction: see text]

Entities:  

Year:  2004        PMID： 14986972     DOI： 10.1021/ol036501h

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Adaptive organic nanoparticles of a teflon-coated iron (III) porphyrin catalytically activate dioxygen for cyclohexene oxidation.

Authors:  Amit Aggarwal; Sunaina Singh; Jacopo Samson; Charles Michael Drain
Journal:  Macromol Rapid Commun       Date:  2012-04-20       Impact factor: 5.734

2.  Allylic oxidations catalyzed by dirhodium caprolactamate via aqueous tert-butyl hydroperoxide: the role of the tert-butylperoxy radical.

Authors:  Emily C McLaughlin; Hojae Choi; Kan Wang; Grace Chiou; Michael P Doyle
Journal:  J Org Chem       Date:  2009-01-16       Impact factor: 4.354

3.  Optimal TBHP allylic oxidation of Delta5-steroids catalyzed by dirhodium caprolactamate.

Authors:  Hojae Choi; Michael P Doyle
Journal:  Org Lett       Date:  2007-11-21       Impact factor: 6.005

4.  Asymmetric Synthesis of Oxygenated Monoterpenoids of Importance for Bark Beetle Ecology.

Authors:  Suresh Ganji; Fredric G Svensson; C Rikard Unelius
Journal:  J Nat Prod       Date:  2020-11-10       Impact factor: 4.050
  4 in total

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